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A sample of 2.30 g of ethanol was mixed with an excess of aqueous acidified potassium dichromate (VI) and refluxed to give ethanoic acid. If the yield of product collected was 60.0%, what mass of product was collected?(Ethanol = 46, Ethanoic acid = 60)

Chemistry

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Answer

1.8 g\text{1.8 g}

Step-by-step solution

5 steps
  1. Write the balanced chemical equation for the oxidation of ethanol to ethanoic acid.

    Ethanol (CH3CH2OH\text{CH}_3\text{CH}_2\text{OH}) is oxidized to ethanoic acid (CH3COOH\text{CH}_3\text{COOH}) using an oxidizing agent like acidified potassium dichromate(VI). The balanced equation is:

    CH3CH2OH+2[O]⟶CH3COOH+H2O\text{CH}_3\text{CH}_2\text{OH} + 2[\text{O}] \longrightarrow \text{CH}_3\text{COOH} + \text{H}_2\text{O}

    From the equation, 1 mole of ethanol produces 1 mole of ethanoic acid.

  2. Calculate the moles of ethanol.

    The molar mass of ethanol (C2H5OH\text{C}_2\text{H}_5\text{OH}) is given as 46 g/mol.
    The mass of ethanol is 2.30 g.

    Moles of ethanol=MassMolar mass=2.30 g46 g/mol=0.050 mol\text{Moles of ethanol} = \frac{\text{Mass}}{\text{Molar mass}} = \frac{2.30 \text{ g}}{46 \text{ g/mol}} = 0.050 \text{ mol}
  3. Determine the theoretical moles of ethanoic acid.

    Since the mole ratio of ethanol to ethanoic acid is 1:1, the theoretical moles of ethanoic acid produced will be equal to the moles of ethanol.

    Theoretical moles of ethanoic acid=0.050 mol\text{Theoretical moles of ethanoic acid} = 0.050 \text{ mol}
  4. Calculate the theoretical mass of ethanoic acid.

    The molar mass of ethanoic acid (CH3COOH\text{CH}_3\text{COOH}) is given as 60 g/mol.

    Theoretical mass of ethanoic acid=Moles×Molar mass=0.050 mol×60 g/mol=3.0 g\text{Theoretical mass of ethanoic acid} = \text{Moles} \times \text{Molar mass} = 0.050 \text{ mol} \times 60 \text{ g/mol} = 3.0 \text{ g}
  5. Calculate the actual mass of ethanoic acid collected using the given yield.

    The yield of the product was 60.0%.

    Actual mass collected=Theoretical mass×Yield100%=3.0 g×60.0100=1.8 g\text{Actual mass collected} = \text{Theoretical mass} \times \frac{\text{Yield}}{100\%} = 3.0 \text{ g} \times \frac{60.0}{100} = 1.8 \text{ g}

    The mass of product collected was 1.8 g.

    1.8 g\text{1.8 g}
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