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Explain how an increase in reactant concentration affects reaction rate, and calculate the moles of sulfur produced from 1.62g of sulfur in the reaction between Na2S2O3 and HCl.

Chemistry

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Answer

7.99 g\text{7.99 g}

Step-by-step solution

6 steps
  1. Address Question 11.5.

    According to the collision theory, an increase in the concentration of reactants affects the reaction rate as follows:

    • An increase in concentration means there are more reactant particles per unit volume.
    • This leads to an increase in the frequency of collisions between the reactant particles.
    • Consequently, there will be a higher number of effective collisions per unit time (collisions with sufficient energy and correct orientation).
    • A greater number of effective collisions per unit time results in an increased rate of reaction.
  2. Address Question 11.6.

    First, write the balanced chemical equation for the reaction:

    Na2S2O3(aq)+2HCl(aq)→2NaCl(aq)+SO2(g)+S(s)+H2O(l)\text{Na}_2\text{S}_2\text{O}_3\text{(aq)} + \text{2HCl(aq)} \to \text{2NaCl(aq)} + \text{SO}_2\text{(g)} + \text{S(s)} + \text{H}_2\text{O(l)}

    From the equation, 1 mole of Na2_2S2_2O3_3 produces 1 mole of S.

  3. Calculate the molar masses.

    Molar mass of Sulphur (S) = 32.07 g/mol
    Molar mass of Sodium thiosulphate (Na2_2S2_2O3_3) = (2 ×\times 22.99) + (2 ×\times 32.07) + (3 ×\times 16.00) = 45.98 + 64.14 + 48.00 = 158.12 g/mol

  4. Calculate the moles of sulphur produced.

    Given mass of S = 1.62 g

    Moles of S=Mass of SMolar mass of S\text{Moles of S} = \frac{\text{Mass of S}}{\text{Molar mass of S}} Moles of S=1.62 g32.07 g/mol≈0.0505145 mol\text{Moles of S} = \frac{1.62 \text{ g}}{32.07 \text{ g/mol}} \approx 0.0505145 \text{ mol}
  5. Calculate the moles of sodium thiosulphate used.

    From the balanced equation, the mole ratio of Na2_2S2_2O3_3 to S is 1:1.

    Moles of Na2S2O3=Moles of S≈0.0505145 mol\text{Moles of Na}_2\text{S}_2\text{O}_3 = \text{Moles of S} \approx 0.0505145 \text{ mol}
  6. Calculate the mass of sodium thiosulphate used.

    Mass of Na2S2O3=Moles of Na2S2O3×Molar mass of Na2S2O3\text{Mass of Na}_2\text{S}_2\text{O}_3 = \text{Moles of Na}_2\text{S}_2\text{O}_3 \times \text{Molar mass of Na}_2\text{S}_2\text{O}_3 Mass of Na2S2O3=0.0505145 mol×158.12 g/mol\text{Mass of Na}_2\text{S}_2\text{O}_3 = 0.0505145 \text{ mol} \times 158.12 \text{ g/mol} Mass of Na2S2O3≈7.987 g\text{Mass of Na}_2\text{S}_2\text{O}_3 \approx 7.987 \text{ g}

    Rounding to two decimal places:
    The mass of the sodium thiosulphate used in experiment 1 is 7.99 g\boxed{\text{7.99 g}}.

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