Alright — let's do this.
The question asks for an organic compound that does not react with both hydrogen cyanide (HCN) and hydroxylamine (NH2OH).
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Reaction with Hydrogen Cyanide (HCN): Hydrogen cyanide undergoes nucleophilic addition reactions with compounds containing a carbonyl group (C=O), specifically aldehydes and ketones, to form cyanohydrins.
- Alkanones (ketones) have a C=O group and react with HCN.
- Alkanals (aldehydes) have a C=O group and react with HCN.
- Alkanoic acids have a C=O group as part of a carboxyl group (COOH), but their carbonyl carbon is less reactive towards nucleophilic addition compared to aldehydes and ketones, so they generally do not form cyanohydrins.
- Alkenes have a carbon-carbon double bond (C=C) but no C=O group, so they do not react with HCN in this manner.
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Reaction with Hydroxylamine (NH2OH): Hydroxylamine reacts with compounds containing a carbonyl group (C=O), specifically aldehydes and ketones, to form oximes. This is a nucleophilic addition-elimination reaction.
- Alkanones (ketones) have a C=O group and react with NH2OH.
- Alkanals (aldehydes) have a C=O group and react with NH2OH.
- Alkanoic acids do not typically react with hydroxylamine to form oximes at the carboxyl carbon.
- Alkenes have no C=O group, so they do not react with NH2OH to form oximes.
Based on this analysis:
- Alkanones and Alkanals react with both HCN and NH2OH.
- Alkanoic acids generally do not undergo these specific reactions.
- Alkenes do not have a carbonyl group (C=O) and therefore do not undergo these characteristic reactions with either HCN or NH2OH.
Thus, an alkene is the compound that does not undergo a reaction with both hydrogen cyanide and hydroxylamine.
The correct option is B.