How to calculate half life in chemistry

Chemistry

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The half-life (t1/2t_{1/2}) of a chemical reaction is the time required for the concentration of a reactant to decrease to half of its initial value. The formula for half-life depends on the order of the reaction.

For a first-order reaction:

t1/2=ln⁡(2)kt_{1/2} = \frac{\ln(2)}{k}

where kk is the rate constant.

For a second-order reaction (where the rate depends on the square of the concentration of one reactant, or the product of the concentrations of two reactants):

t1/2=1k[A]0t_{1/2} = \frac{1}{k[A]_0}

where kk is the rate constant and [A]0[A]_0 is the initial concentration of the reactant.

For a zero-order reaction:

t1/2=[A]02kt_{1/2} = \frac{[A]_0}{2k}

where kk is the rate constant and [A]0[A]_0 is the initial concentration of the reactant.

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