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Describe the industrial preparation of nitric (V) acid using the Ostwald process, including the chemical equations for each step.

Chemistry

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  1. The following is a flowchart that shows the industrial preparation of nitric (V) acid. (Since I cannot draw a flowchart, I will describe the steps sequentially.) Industrial Preparation of Nitric (V) Acid (Ostwald Process)
  1. Catalytic Oxidation of Ammonia

    Ammonia ($\text{NH}_3$) and air (source of $\text{O}_2$) are mixed and passed over a heated **platinum-rhodium catalyst** at about $800-900^\circ\text{C}$ and $4-10$ atmospheres pressure. This produces nitric oxide ($\text{NO}$) and water.
    $$
    4\text{NH}_3\text{(g)} + 5\text{O}_2\text{(g)} \xrightarrow{\text{Pt/Rh catalyst}} 4\text{NO(g)} + 6\text{H}_2\text{O(g)}
    $$
    
  2. Oxidation of Nitric Oxide

    The hot nitric oxide is cooled and then reacted with excess air (oxygen) in an oxidation chamber. This converts nitric oxide to nitrogen dioxide ($\text{NO}_2$).
    $$
    2\text{NO(g)} + \text{O}_2\text{(g)} \rightarrow 2\text{NO}_2\text{(g)}
    $$
    
  3. Absorption of Nitrogen Dioxide in Water

    The nitrogen dioxide is then passed into an absorption tower where it reacts with water, usually sprayed from the top. This forms nitric (V) acid ($\text{HNO}_3$) and regenerates nitric oxide ($\text{NO}$).
    $$
    3\text{NO}_2\text{(g)} + \text{H}_2\text{O(l)} \rightarrow 2\text{HNO}_3\text{(aq)} + \text{NO(g)}
    $$
    
  4. Recycling of Nitric Oxide

    The nitric oxide ($\text{NO}$) produced in the absorption tower is recycled back to the oxidation chamber (Step 2) to be re-oxidized to nitrogen dioxide, making the process more efficient.
    
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