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Determine the oxidation states of Cr and C in the reactants and products.

Chemistry

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1a)

  1. Determine the oxidation states of Cr and C in the reactants and products.

    In Cr2O72−\text{Cr}_2\text{O}_7^{2-}: 2(Cr)+7(−2)=−2⇒2(Cr)=+12⇒Cr=+62(\text{Cr}) + 7(-2) = -2 \Rightarrow 2(\text{Cr}) = +12 \Rightarrow \text{Cr} = +6.
    In Cr3+\text{Cr}^{3+}: Cr=+3\text{Cr} = +3.
    Chromium's oxidation state decreases from +6+6 to +3+3, so Cr2O72−\text{Cr}_2\text{O}_7^{2-} is reduced.

    In C2O42−\text{C}_2\text{O}_4^{2-}: 2(C)+4(−2)=−2⇒2(C)=+6⇒C=+32(\text{C}) + 4(-2) = -2 \Rightarrow 2(\text{C}) = +6 \Rightarrow \text{C} = +3.
    In CO2\text{CO}_2: C+2(−2)=0⇒C=+4\text{C} + 2(-2) = 0 \Rightarrow \text{C} = +4.
    Carbon's oxidation state increases from +3+3 to +4+4, so C2O42−\text{C}_2\text{O}_4^{2-} is oxidized.

  2. Identify the oxidizing and reducing agents.

    The species that is reduced is the oxidizing agent.
    The species that is oxidized is the reducing agent.

    • Oxidizing agent: Cr2O72−\boxed{\text{Cr}_2\text{O}_7^{2-}}
    • Reducing agent: C2O42−\boxed{\text{C}_2\text{O}_4^{2-}}

    1b)
    The given reaction is:

    Cr2O72−+C2O42−+H+→Cr3++CO2+H2O\text{Cr}_2\text{O}_7^{2-} + \text{C}_2\text{O}_4^{2-} + \text{H}^+ \rightarrow \text{Cr}^{3+} + \text{CO}_2 + \text{H}_2\text{O}
  3. Write the unbalanced half-reactions.

    Oxidation: C2O42−→CO2\text{C}_2\text{O}_4^{2-} \rightarrow \text{CO}_2
    Reduction: Cr2O72−→Cr3+\text{Cr}_2\text{O}_7^{2-} \rightarrow \text{Cr}^{3+}

  4. Balance atoms other than O and H.

    Oxidation: C2O42−→2CO2\text{C}_2\text{O}_4^{2-} \rightarrow 2\text{CO}_2
    Reduction: Cr2O72−→2Cr3+\text{Cr}_2\text{O}_7^{2-} \rightarrow 2\text{Cr}^{3+}

  5. Balance O atoms by adding H2O\text{H}_2\text{O}.

    Oxidation: C2O42−→2CO2\text{C}_2\text{O}_4^{2-} \rightarrow 2\text{CO}_2 (O atoms are already balanced)
    Reduction: Cr2O72−→2Cr3++7H2O\text{Cr}_2\text{O}_7^{2-} \rightarrow 2\text{Cr}^{3+} + 7\text{H}_2\text{O}

  6. Balance H atoms by adding H+\text{H}^+ (since it's an acidic medium).

    Oxidation: C2O42−→2CO2\text{C}_2\text{O}_4^{2-} \rightarrow 2\text{CO}_2 (H atoms are already balanced)
    Reduction: 14H++Cr2O72−→2Cr3++7H2O14\text{H}^+ + \text{Cr}_2\text{O}_7^{2-} \rightarrow 2\text{Cr}^{3+} + 7\text{H}_2\text{O}

  7. Balance charge by adding electrons (e−\text{e}^-).

    Oxidation: C2O42−→2CO2+2e−\text{C}_2\text{O}_4^{2-} \rightarrow 2\text{CO}_2 + 2\text{e}^- (Charge: −2-2

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