Here are the answers to your questions:
1a)
Step 1: Determine the oxidation states of Cr and C in the reactants and products.
In Cr2O72−: 2(Cr)+7(−2)=−2⇒2(Cr)=+12⇒Cr=+6.
In Cr3+: Cr=+3.
Chromium's oxidation state decreases from +6 to +3, so Cr2O72− is reduced.
In C2O42−: 2(C)+4(−2)=−2⇒2(C)=+6⇒C=+3.
In CO2: C+2(−2)=0⇒C=+4.
Carbon's oxidation state increases from +3 to +4, so C2O42− is oxidized.
Step 2: Identify the oxidizing and reducing agents.
The species that is reduced is the oxidizing agent.
The species that is oxidized is the reducing agent.
- Oxidizing agent: Cr2O72−
- Reducing agent: C2O42−
1b)
The given reaction is:
Cr2O72−+C2O42−+H+→Cr3++CO2+H2O
Step 1: Write the unbalanced half-reactions.
Oxidation: C2O42−→CO2
Reduction: Cr2O72−→Cr3+
Step 2: Balance atoms other than O and H.
Oxidation: C2O42−→2CO2
Reduction: Cr2O72−→2Cr3+
Step 3: Balance O atoms by adding H2O.
Oxidation: C2O42−→2CO2 (O atoms are already balanced)
Reduction: Cr2O72−→2Cr3++7H2O
Step 4: Balance H atoms by adding H+ (since it's an acidic medium).
Oxidation: C2O42−→2CO2 (H atoms are already balanced)
Reduction: 14H++Cr2O72−→2Cr3++7H2O
Step 5: Balance charge by adding electrons (e−).
Oxidation: C2O42−→2CO2+2e− (Charge: −2