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Describe the process of standardizing hydrochloric acid (Solution A) using sodium hydrogen carbonate and the calculations involved.

Chemistry

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This problem involves preparing a standard solution, performing titrations, and calculating concentrations. Since no experimental data is provided, the calculations will be demonstrated using example values, and the procedures will be described.

Given:

  • Sodium hydrogen carbonate (NaHCO3_{3})
  • Solution A: Hydrochloric acid (HCl)
  • Solution B: Aqueous Sodium hydroxide (NaOH)
  • Indicators: Phenolphthalein, Methyl orange

Molar mass of Sodium hydrogen carbonate (NaHCO3_{3}):
Na: 22.99 g/mol22.99 \text{ g/mol}
H: 1.01 g/mol1.01 \text{ g/mol}
C: 12.01 g/mol12.01 \text{ g/mol}
O: 16.00 g/mol16.00 \text{ g/mol}

Molar mass of NaHCO3=22.99+1.01+12.01+(3×16.00)=84.01 g/mol\text{Molar mass of NaHCO}_3 = 22.99 + 1.01 + 12.01 + (3 \times 16.00) = 84.01 \text{ g/mol}

a) Make up a solution of Sodium hydrogen carbonate and use it to standardize solution A.

  1. Prepare the standard Sodium hydrogen carbonate solution.

    • Weigh accurately between 2.01 g2.01 \text{ g} and 2.08 g2.08 \text{ g} of solid Sodium hydrogen carbonate using a weighing boat or watch glass. Record the exact mass. (For demonstration, let's assume a mass of 2.05 g2.05 \text{ g}).
    • Transfer the weighed NaHCO3_{3} quantitatively into a 250 cm3250 \text{ cm}^3 volumetric flask. Use a funnel to avoid spillage and rinse the weighing boat/watch glass and funnel with distilled water into the flask.
    • Add distilled water to the flask, swirling gently to dissolve the solid.
    • Once dissolved, add more distilled water until the bottom of the meniscus aligns with the 250 cm3250 \text{ cm}^3 mark on the volumetric flask. Ensure your eye is at the same level as the meniscus.
    • Stopper the flask and invert it several times to ensure the solution is thoroughly mixed and homogeneous. This is your standard Sodium hydrogen carbonate solution.
  2. Standardize Solution A (Hydrochloric acid) using the standard Sodium hydrogen carbonate solution.

    • Rinse a burette with Solution A (HCl) and then fill it with Solution A. Ensure no air bubbles are trapped and the initial reading is recorded.
    • Rinse a 25.0 cm325.0 \text{ cm}^3 pipette with the standard NaHCO3_{3} solution and then pipette
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