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Calculate the ratio of HPO4(2-) to H2PO4(-) in a buffer solution at pH 7.44, given the Ka of H2PO4(-) is 6.2 x 10⁻⁸.

Chemistry

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Here are the solutions for parts (a), (b), and (c).

The buffer system involves dihydrogen phosphate (H2PO4−H_2PO_4^-) as the acid (HA) and hydrogen phosphate (HPO42−HPO_4^{2-} ) as its conjugate base (A−A^-).
The equilibrium is:
H2PO4−(aq)⇌H+(aq)+HPO42−(aq)H_2PO_4^- (aq) \rightleftharpoons H^+ (aq) + HPO_4^{2-} (aq)

Given:
pH = 7.44
Ka=6.2×10−8K_a = 6.2 \times 10^{-8}

First, calculate the pKapK_a:

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