The volume and molarity of sodium hydroxide (NaOH) were determined through a titration experiment using potassium hydrogen phthalate (KHP) as a primary standard.
Step 1: Determine the volume of NaOH used in cm³.
The volume of NaOH used for each trial was calculated by subtracting the initial burette reading from the final burette reading.
- Trial 1:
VolumeofNaOH=10.20cm3−0.00cm3=10.20cm3
- Trial 2:
VolumeofNaOH=11.90cm3−0.00cm3=11.90cm3
- Trial 3:
VolumeofNaOH=23.60cm3−11.90cm3=11.70cm3
Step 2: Convert the volume of NaOH from cm³ to Liters (L).
To convert cm³ to Liters, divide by 1000cm3/L.
- Trial 1:
VolumeofNaOH=1000cm3/L10.20cm3=0.0102L
- Trial 2:
VolumeofNaOH=1000cm3/L11.90cm3=0.0119L
- Trial 3:
VolumeofNaOH=1000cm3/L11.70cm3=0.0117L
Step 3: Calculate the moles of KHP used in each trial.
The moles of KHP were calculated using its mass and molar mass (204.24 g/mol).
MolesofKHP=MolarmassofKHPMassofKHP
- Trial 1:
MolesofKHP=204.24g/mol0.21900g=0.00107mol
- Trial 2:
MolesofKHP=204.24g/mol0.28900g=0.00141mol
- Trial 3:
MolesofKHP=204.24g/mol0.22000g=0.00108mol
Step 4: Determine the molarity of NaOH for each trial.
Since KHP is a monoprotic acid and reacts with NaOH in a 1:1 mole ratio, the moles of NaOH at the equivalence point are equal to the moles of KHP.
MolarityofNaOH=VolumeofNaOH(L)MolesofNaOH
- Trial 1:
MolarityofNaOH=0.0102L0.00107mol=0.105M
- Trial 2:
MolarityofNaOH=0.0119L0.00141mol=0.118M
- Trial 3:
MolarityofNaOH=0.0117L0.00108mol=0.092M
Step 5: Calculate the average molarity of NaOH.
The average molarity was found by summing the molarities from each trial and dividing by the number of trials.
AverageMolarityofNaOH=30.105M+0.118M+0.092M=30.315M=0.105 M