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1 Define a Compound 7.2 Calculate the percentage of chromium in K2Cr2O7. 7.3 An inorganic substance was analysed and found to be containing 65,31% of oxygen, 32,65% of Sulphur and 2,04% of hydrogen. 7.3.1 Define an empirical formula. 7.3.2 Determine the empirical formula for the compound.

Chemistry

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Answer

35.35%\text{35.35\%}

H2SO4\text{H}_2\text{SO}_4

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here are the solutions to your chemistry questions:

7.1. A compound is a substance formed when two or more different chemical elements are chemically bonded together in a fixed ratio.

7.2. To calculate the percentage of chromium in K₂Cr₂O₇:

  1. Determine the molar mass of K₂Cr₂O₇.

    The atomic masses are approximately: K = 39.10 g/mol39.10 \text{ g/mol}, Cr = 52.00 g/mol52.00 \text{ g/mol}, O = 16.00 g/mol16.00 \text{ g/mol}.

    Molar mass of K2Cr2O7=(2×39.10)+(2×52.00)+(7×16.00)\text{Molar mass of K}_2\text{Cr}_2\text{O}_7 = (2 \times 39.10) + (2 \times 52.00) + (7 \times 16.00) =78.20+104.00+112.00= 78.20 + 104.00 + 112.00 =294.20 g/mol= 294.20 \text{ g/mol}
  2. Calculate the total mass of chromium in one mole of K₂Cr₂O₇.

    Mass of Cr=2×52.00 g/mol=104.00 g/mol\text{Mass of Cr} = 2 \times 52.00 \text{ g/mol} = 104.00 \text{ g/mol}
  3. Calculate the percentage of chromium.

    Percentage of Cr=Mass of CrMolar mass of K2Cr2O7×100%\text{Percentage of Cr} = \frac{\text{Mass of Cr}}{\text{Molar mass of K}_2\text{Cr}_2\text{O}_7} \times 100\% =104.00 g/mol294.20 g/mol×100%= \frac{104.00 \text{ g/mol}}{294.20 \text{ g/mol}} \times 100\% =35.35%= 35.35\%

    The percentage of chromium in K₂Cr₂O₇ is \boxed{\text{35.35%}}.

    7.3.1. An empirical formula shows the simplest whole-number ratio of atoms of each element in a compound.

    7.3.2. To determine the empirical formula for the compound:

  4. Assume a 100 g100 \text{ g} sample and convert percentages to masses.

    • Mass of Oxygen (O) = 65.31 g65.31 \text{ g}
    • Mass of Sulphur (S) = 32.65 g32.65 \text{ g}
    • Mass of Hydrogen (H) = 2.04 g2.04 \text{ g}
  5. Convert the mass of each element to moles using their atomic masses (O = 16.00 g/mol16.00 \text{ g/mol}, S = 32.07 g/mol32.07 \text{ g/mol}, H = 1.01 g/mol1.01 \text{ g/mol}).

    Moles of O=65.31 g16.00 g/mol=4.08 mol\text{Moles of O} = \frac{65.31 \text{ g}}{16.00 \text{ g/mol}} = 4.08 \text{ mol} Moles of S=32.65 g32.07 g/mol=1.02 mol\text{Moles of S} = \frac{32.65 \text{ g}}{32.07 \text{ g/mol}} = 1.02 \text{ mol} Moles of H=2.04 g1.01 g/mol=2.02 mol\text{Moles of H} = \frac{2.04 \text{ g}}{1.01 \text{ g/mol}} = 2.02 \text{ mol}
  6. Divide each mole value by the smallest number of moles to find the simplest ratio.

    The smallest number of moles is 1.02 mol1.02 \text{ mol} (for Sulphur).

    Ratio for O=4.081.02≈4\text{Ratio for O} = \frac{4.08}{1.02} \approx 4 Ratio for S=1.021.02=1\text{Ratio for S} = \frac{1.02}{1.02} = 1 Ratio for H=2.021.02≈2\text{Ratio for H} = \frac{2.02}{1.02} \approx 2
  7. Write the empirical formula using these whole-number ratios.

    The empirical formula is H2SO4\boxed{\text{H}_2\text{SO}_4}.

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