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Explain why Ka1 > Ka2 > K_a3 for a polyprotic acid like citric acid.
Chemistry
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Part (a): Explain why
The dissociation constants () for a polyprotic acid decrease with each successive proton removal. This trend is due to the increasing difficulty of removing a positively charged proton from an increasingly negatively charged species.
- First dissociation (): The neutral citric acid () loses a proton to form a singly charged anion (). This is the easiest proton to remove because there is no electrostatic attraction between the proton and
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