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Calculate the molarity of NaOH and the concentration of a diluted FeCl3 solution using the provided data.

Chemistry

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1. Molarity of NaOH solution

  1. Calculate the molar mass of KHP (KHC8H4O4\text{KHC}_8\text{H}_4\text{O}_4).

    Molar mass of KHP =(1×39.098)+(5×1.008)+(8×12.011)+(4×15.999)=204.222 g/mol= (1 \times 39.098) + (5 \times 1.008) + (8 \times 12.011) + (4 \times 15.999) = 204.222 \text{ g/mol}

  2. Calculate the moles of KHP.

    Moles of KHP=Mass of KHPMolar mass of KHP=0.8234 g204.222 g/mol=0.0040319 mol\text{Moles of KHP} = \frac{\text{Mass of KHP}}{\text{Molar mass of KHP}} = \frac{0.8234 \text{ g}}{204.222 \text{ g/mol}} = 0.0040319 \text{ mol}
  3. Determine the moles of NaOH.

    The reaction between KHP and NaOH is 1:1.

    KHC8H4O4(aq)+NaOH (aq)→KNaC8H4O4(aq)+H2O (l)\text{KHC}_8\text{H}_4\text{O}_4 \text{(aq)} + \text{NaOH (aq)} \rightarrow \text{KNaC}_8\text{H}_4\text{O}_4 \text{(aq)} + \text{H}_2\text{O (l)}

    Therefore, moles of NaOH = moles of KHP =0.0040319 mol= 0.0040319 \text{ mol}.

  4. Convert the volume of NaOH to liters.

    Volume of NaOH=38.76 cm3=38.76 mL=0.03876 L\text{Volume of NaOH} = 38.76 \text{ cm}^3 = 38.76 \text{ mL} = 0.03876 \text{ L}
  5. Calculate the molarity of the NaOH solution.

    Molarity of NaOH=Moles of NaOHVolume of NaOH (L)=0.0040319 mol0.03876 L=0.10403 M\text{Molarity of NaOH} = \frac{\text{Moles of NaOH}}{\text{Volume of NaOH (L)}} = \frac{0.0040319 \text{ mol}}{0.03876 \text{ L}} = 0.10403 \text{ M}

    The exact molarity of the NaOH solution is 0.1040 M\boxed{\text{0.1040 M}}.

    2. Concentration of the diluted FeCl3\text{FeCl}_3 solution

  6. Identify the given values for dilution.

    Initial concentration (M1M_1) =3.47×10−2 M= 3.47 \times 10^{-2} \text{ M}
    Initial volume (V1V_1) =5.00 cm3= 5.00 \text{ cm}^3
    Final volume (V2V_2) =250 cm3= 250 \text{ cm}^3

  7. Use the dilution formula M1V1=M2V2M_1V_1 = M_2V_2.

    (3.47×10−2 M)×(5.00 cm3)=M2×(250 cm3)(3.47 \times 10^{-2} \text{ M}) \times (5.00 \text{ cm}^3) = M_2 \times (250 \text{ cm}^3)
  8. Solve for M2M_2.

    M2=(3.47×10−2 M)×(5.00 cm3)250 cm3M_2 = \frac{(3.47 \times 10^{-2} \text{ M}) \times (5.00 \text{ cm}^3)}{250 \text{ cm}^3} M2=0.1735 M⋅cm3250 cm3M_2 = \frac{0.1735 \text{ M} \cdot \text{cm}^3}{250 \text{ cm}^3} M2=0.000694 M=6.94×10−4 MM_2 = 0.000694 \text{ M} = 6.94 \times 10^{-4} \text{ M}

    The concentration of the diluted solution is 6.94×10−4 M\boxed{\text{6.94} \times 10^{-4} \text{ M}}.

    3. Molarity of the FeCl3\text{FeCl}_3 (aq) solution

  9. Calculate the molar mass of FeCl3\text{FeCl}_3.

    Molar mass of FeCl3=(1×55.845)+(3×35.453)=55.845+106.359=162.204 g/mol\text{FeCl}_3 = (1 \times 55.845) + (3 \times 35.453) = 55.845 + 106.359 = 162.204 \text{ g/mol}

  10. Calculate the moles of FeCl3\text{FeCl}_3.

    Moles of FeCl3=Mass of FeCl3Molar mass of FeCl3=0.563 g162.204 g/mol=0.0034709 mol\text{Moles of FeCl}_3 = \frac{\text{Mass of FeCl}_3}{\text{Molar mass of FeCl}_3} = \frac{0.563 \text{ g}}{162.204 \text{ g/mol}} = 0.0034709 \text{ mol}
  11. Convert the volume of the solution to liters.

    Volume of solution=100.0 mL=0.1000 L\text{Volume of solution} = 100.0 \text{ mL} = 0.1000 \text{ L}
  12. Calculate the molarity of the FeCl3\text{FeCl}_3 solution.

    Molarity of FeCl3=Moles of FeCl3Volume of solution (L)=0.0034709 mol0.1000 L=0.034709 M\text{Molarity of FeCl}_3 = \frac{\text{Moles of FeCl}_3}{\text{Volume of solution (L)}} = \frac{0.0034709 \text{ mol}}{0.1000 \text{ L}} = 0.034709 \text{ M}

    The molarity of the FeCl3\text{FeCl}_3 (aq) solution is 0.0347 M\boxed{\text{0.0347 M}}.

    4. Concentration of the diluted solution

  13. Identify the given values for dilution.

    Initial concentration (M1M_1) =0.03477 M= 0.03477 \text{ M} (using the provided answer from question 3 for consistency)
    Initial volume (V1V_1) =5.00 cm3= 5.00 \text{ cm}^3
    Final volume (V2V_2) =250 cm3= 250 \text{ cm}^3

  14. Use the dilution formula M1V1=M2V2M_1V_1 = M_2V_2.

    (0.03477 M)×(5.00 cm3)=M2×(250 cm3)(0.03477 \text{ M}) \times (5.00 \text{ cm}^3) = M_2 \times (250 \text{ cm}^3)
  15. Solve for M2M_2.

    M2=(0.03477 M)×(5.00 cm3)250 cm3M_2 = \frac{(0.03477 \text{ M}) \times (5.00 \text{ cm}^3)}{250 \text{ cm}^3} M2=0.17385 M⋅cm3250 cm3M_2 = \frac{0.17385 \text{ M} \cdot \text{cm}^3}{250 \text{ cm}^3} M2=0.0006954 MM_2 = 0.0006954 \text{ M}

    The concentration of the diluted solution is 0.0006954 M\boxed{\text{0.0006954 M}}.

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