What are the signs of heat quantity in exothermic and endothermic reaction and why those signs

Chemistry

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In thermodynamics, the sign of the heat quantity (qq or ΔH\Delta H) indicates the direction of heat flow relative to the system (the reaction).

  • Exothermic reactions: The sign of the heat quantity is negative (q<0q < 0 or ΔH<0\Delta H < 0).

    • Why: Exothermic reactions release heat energy to the surroundings. This means the system (the reacting chemicals) loses energy. By convention, when a system loses energy in the form of heat, the heat quantity is assigned a negative sign.
  • Endothermic reactions: The sign of the heat quantity is positive (q>0q > 0 or ΔH>0\Delta H > 0).

    • Why: Endothermic reactions absorb heat energy from the surroundings. This means the system (the reacting chemicals) gains energy. By convention, when a system gains energy in the form of heat, the heat quantity is assigned a positive sign.
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