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The solutions provided cover nuclear equations for decay, defining half-life, and calculating remaining radioactive material after a certain time.

Chemistry

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4.

a) Write a nuclear equation for the decay process.

  1. Identify the parent nucleus (X), daughter nucleus (22688Ra\frac{226}{88}Ra), and emitted particle (alpha, α\alpha).

    An alpha particle is represented as 42He\frac{4}{2}He.
    Let the parent nucleus be AZX\frac{A}{Z}X.

  2. Write the general decay equation.

    AZX⟶22688Ra+42He\frac{A}{Z}X \longrightarrow \frac{226}{88}Ra + \frac{4}{2}He
  3. Conserve the mass number (A) and atomic number (Z).

    For mass number: A=226+4=230A = 226 + 4 = 230
    For atomic number: Z=88+2=90Z = 88 + 2 = 90

  4. Write the complete nuclear equation.

    23090Th⟶22688Ra+42He\boxed{\frac{230}{90}Th \longrightarrow \frac{226}{88}Ra + \frac{4}{2}He}

    b) Determine the mass and atomic number of X.

    From the nuclear equation in part (a):

    • Mass number of X is 230.
    • Atomic number of X is 90.

    5.

    a) Define the term half-life.

    Half-life is the time taken for half of the radioactive nuclei in a sample to decay, or for the activity of a radioactive sample to fall to half its original value.

    b) The half-life of 23592U\frac{235}{92}U is 4500 years. Work out the fraction of radioactive material that would be remaining after 18000 years.

  5. Calculate the number of half-lives (nn).

    n=Total timeHalf-life=18000 years4500 years=4n = \frac{\text{Total time}}{\text{Half-life}} = \frac{18000 \text{ years}}{4500 \text{ years}} = 4

    The substance undergoes 4 half-lives.

  6. Calculate the fraction remaining.

    The fraction remaining is given by the formula (12)n\left(\frac{1}{2}\right)^n.

    Fraction remaining=(12)4=12×2×2×2=116\text{Fraction remaining} = \left(\frac{1}{2}\right)^4 = \frac{1}{2 \times 2 \times 2 \times 2} = \frac{1}{16}

    The fraction of radioactive material remaining is 116\boxed{\frac{1}{16}}.

    6.

    a) Determine the value of m and n in the nuclear equation:

    21684Po⟶20882Pb+mα+nβ\frac{216}{84}Po \longrightarrow \frac{208}{82}Pb + m\alpha + n\beta
  7. Identify the particles.

    An alpha particle (α\alpha) is 42He\frac{4}{2}He.
    A beta particle (β\beta) is 0−1e\frac{0}{-1}e.

  8. Substitute the particles into the equation.

    21684Po⟶20882Pb+m42He+n0−1e\frac{216}{84}Po \longrightarrow \frac{208}{82}Pb + m\frac{4}{2}He + n\frac{0}{-1}e
  9. Conserve the mass number.

    216=208+m(4)+n(0)216 = 208 + m(4) + n(0) 216=208+4m216 = 208 + 4m 4m=216−2084m = 216 - 208 4m=84m = 8 m=84=2m = \frac{8}{4} = 2
  10. Conserve the atomic number.

    84=82+m(2)+n(−1)84 = 82 + m(2) + n(-1)

    Substitute the value of m=2m=2:

    84=82+2(2)−n84 = 82 + 2(2) - n 84=82+4−n84 = 82 + 4 - n 84=86−n84 = 86 - n n=86−84n = 86 - 84 n=2n = 2

    The values are m=2,n=2\boxed{m=2, n=2}.

    b) The table below gives the rate of decay of radioactive element Y. Calculate the half-life of element Y.

  11. Identify the initial mass (N0N_0) and final mass (NtN_t).

    At 0 days, N0=48 gramsN_0 = 48 \text{ grams}.
    At 270 days, Nt=1.5 gramsN_t = 1.5 \text{ grams}.

  12. Use the decay formula Nt=N0(12)nN_t = N_0 \left(\frac{1}{2}\right)^n to find the number of half-lives (nn).

    1.5=48(12)n1.5 = 48 \left(\frac{1}{2}\right)^n 1.548=(12)n\frac{1.5}{48} = \left(\frac{1}{2}\right)^n 15480=(12)n\frac{15}{480} = \left(\frac{1}{2}\right)^n 132=(12)n\frac{1}{32} = \left(\frac{1}{2}\right)^n

    Since 25=322^5 = 32, then (12)5=132\left(\frac{1}{2}\right)^5 = \frac{1}{32}.
    Therefore, n=5n = 5.

  13. Calculate the half-life (T1/2T_{1/2}).

    T1/2=Total timen=270 days5=54 daysT_{1/2} = \frac{\text{Total time}}{n} = \frac{270 \text{ days}}{5} = 54 \text{ days}

    The half-life of element Y is 54 days\boxed{\text{54 days}}.

    7. Distinguish between nuclear fission and nuclear fusion.

    • Nuclear fission is the process where a heavy atomic nucleus splits into two or more lighter nuclei, releasing a large amount of energy.
    • Nuclear fusion is the process where two or more light atomic nuclei combine to form a heavier nucleus, also releasing a large amount of energy.

    8.

    a) State one use of radioisotopes in agriculture.

    One use is pest control (e.g., sterile insect technique) or tracing nutrient uptake by plants.

    b) State one danger associated with exposure of human beings to radioisotopes.

    One danger is causing cancer (e.g., leukemia, thyroid cancer) or genetic mutations.

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