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Calculate the work done on 16.0 g of oxygen gas at 100 degrees C that is compressed isothermally to half its initial volume.

Physics

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Answer

1074 J1074 \text{ J}

Step-by-step solution

4 steps
  1. Convert the temperature from Celsius to Kelvin.

    The given temperature is 100∘C100^\circ\text{C}.

    T=100∘C+273.15=373.15 KT = 100^\circ\text{C} + 273.15 = 373.15 \text{ K}
  2. Calculate the number of moles of Oxygen gas (O2\text{O}_2).

    The mass of Oxygen gas is 16.0 g16.0 \text{ g}.
    The molar mass of Oxygen gas (O2\text{O}_2) is 2×16.00 g/mol=32.00 g/mol2 \times 16.00 \text{ g/mol} = 32.00 \text{ g/mol}.

    n=massmolar mass=16.0 g32.00 g/mol=0.50 moln = \frac{\text{mass}}{\text{molar mass}} = \frac{16.0 \text{ g}}{32.00 \text{ g/mol}} = 0.50 \text{ mol}
  3. Apply the formula for work done during isothermal compression.

    For an isothermal process, the work done on the gas is given by:

    W=nRTln⁡(ViVf)W = nRT \ln\left(\frac{V_i}{V_f}\right)

    Where:
    nn is the number of moles
    RR is the ideal gas constant (8.314 J/(mol⋅K)8.314 \text{ J/(mol}\cdot\text{K)})
    TT is the temperature in Kelvin
    ViV_i is the initial volume
    VfV_f is the final volume

    The problem states that the volume is halved, so Vf=12ViV_f = \frac{1}{2}V_i.
    Therefore, ViVf=Vi12Vi=2\frac{V_i}{V_f} = \frac{V_i}{\frac{1}{2}V_i} = 2.

  4. Substitute the values and calculate the work done.

    W=(0.50 mol)×(8.314 J/(mol⋅K))×(373.15 K)×ln⁡(2)W = (0.50 \text{ mol}) \times (8.314 \text{ J/(mol}\cdot\text{K)}) \times (373.15 \text{ K}) \times \ln(2) W=0.50×8.314×373.15×0.693147W = 0.50 \times 8.314 \times 373.15 \times 0.693147 W≈1074.00 JW \approx 1074.00 \text{ J}

    Rounding to the nearest whole number, the work done is 1074 J1074 \text{ J}.

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