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Which of the following pairs of enthalpy changes is always negative?

Chemistry

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Answer

D

6.
The correct option is D.

  • Enthalpy of combustion (ΔHc\Delta H_c) is always negative because combustion reactions are always exothermic, releasing heat.
  • Enthalpy of neutralization (ΔHneut\Delta H_{neut}) is always negative because the reaction between an acid and a base is always exothermic.
  • Enthalpy of formation (ΔHf\Delta H_f) can be positive (endothermic) or negative (exothermic).
  • Enthalpy of solution (ΔHsol\Delta H_{sol}) can be positive (endothermic) or negative (exothermic).

7.
The correct option is D.

  • Covalent compounds are formed between two non-metal atoms by sharing electrons.
  • HCl consists of hydrogen (non-metal) and chlorine (non-metal), forming a covalent bond.
  • MgCl2_2, KCl, and NaCl are all ionic compounds formed between a metal (Mg, K, Na) and a non-metal (Cl).

8.
The correct option is A.

  • A soapy touch is a characteristic property of basic solutions.
  • Basic solutions have a pH greater than 7. Among the given options, 12 is the only pH value that indicates a strongly basic solution.

9.
The correct option is C.

  • Element X has a valency of +3, meaning it forms an ion X3+^{3+}.
  • Chlorine (Cl) has a valency of -1, meaning it forms an ion Cl−^{-}.
  • To form a neutral compound, one X3+^{3+} ion will combine with three Cl−^{-} ions.
  • Therefore, the formula is XCl3_3.

10.
The correct option is B.

  • According to Avogadro's Law, equal volumes of all gases at the same temperature and pressure contain the same number of molecules.
  • CH4(g)_{4(g)} and NH3(g)_{3(g)} are both gases, and if they have equal volumes at the same temperature and pressure, they must contain the same number of molecules.
  • They would not have the same number of atoms because CH4_4 has 5 atoms per molecule, and NH3_3 has 4 atoms per molecule.
  • Their rates of diffusion would be different due to their different molar masses (CH4_4 = 16 g/mol, NH3_3 = 17 g/mol).
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